Got the file OK, and the data looks fine. You seem to have done the tests right.
Just glancing through initially, but the first thing that sticks out, is the imbalance between your left and right channels. Some of it seems to be room symmetry (I noted the "kink" at the rear), because it changes as you add more treatment to the room, but some does not change at all, so that is most likely the signal path itself: Speakers with different settings? Speakers and/or mix position not set up symmetrically in the room? The biggest issue there is a 5 dB peak centered at around 5 kHz., but covering 2k to 12k, roughly. Not sure what that is...
Second, there's no low end. I'm assuming that's just the speakers themselves: The response rolls of steeply below about 45 Hz, and by 40 Hz it's already 12 dB down. If you want to use your setup for serious contemporary music (bass heavy), then you might want to consider getting a sub... or even a pair of subs. Subs are good not just to fill in the low end, but they can also deal with some of the acoustic problems in your room.
For example, you have a fairly major dip between about 115 Hz and 170 Hz. Some of that is probably modal, some is SBIR, some is floor bounce... but all of that could be greatly improved with a pair of subs set up as a plane wave array. We are in the process of doing that right now for a room in New Orleans... (results coming in the next few days, hopefully). I'd suggest that you get a pair of good subs, that you can then re-use for the new studio.
If you compare all of your REW FR graphs at once (see below), you can clearly see the dip I'm talking about:
Alan--tempCR--REW--FR-20-500--all--low-dip.png
You can see the large dip centered around 145 Hz. And you can see that it hardly changes at all with treatment... so my guess is SBIR and floor bounce: the dip is in the region where both of those would be in your room. If you can give me the exact locations of where you had the speakers and mic, then I can figure it more accurately. But anyway, a pair of subs set up for plane wave can have a big impact on your entire low end. The AX7's are nice, but they don't go very low. Mate those with good subs, tweak and tune, and you have a really nice setup.
On that same graph (above) you can see that there's a general lack of bass trapping in your room. Your rear traps are having some effect on the 100 Hz issue and the 178Hz issue, and even smooths out the 80 Hz region a bit, but below about 75 Hz, nothing budges. The 62 Hz monster is standing his ground, not yielding an inch! So your traps are not deep enough, or not placed correctly, or the insulation you are using isn't suitable. Or maybe a tuned trap would be a better bet. But do be warned! Tuning traps is not as easy as the text books make it look...
So, I'd suggest more bass trapping... but the problem is that the place where it needs to go, is all glass! Most of your wall is windows... I'm afraid that some of those are going to need covering up. Maybe bass traps in wheels?
Anyway, on to some comments about your first post:
I fancy a little project to try and treat it as best I can. I have no expectations of it ever being a great room (not least because of the isolation problems)
... and the low ceiling. Oh, and the ceiling is also a bit low. Plus, the ceiling isn0t very high. Not sure if I mentioned that the ceiling elevation is an issue?

But perhaps not as a big an issue as the lack of ceiling height...
However, I now know that the desk was WAY too big,
Ummm... Yup! I won't argue with that! Not in the least!
the speaker stands caused more problems than they solved, the space for rack gear wasn't necessary and the top is so flexible that it actually resonates like an acoustic guitar

I will be trimming it down tomorrow
Ummm... Rather than just trimming it down, I'd suggest building a whole new desk: low profile, open, suitably angled surfaces... I could modify one of my desk designs for you. Build it nicely, and you can re-use it for the new studio as well.... But the big question is: are you planning to keep the Mackie 8-bus? That's a pretty big console (looks like the 24.8, if I'm not wrong, but it might be the 32.

. If you want to keep that for now and the future, then the desk needs to be fairly wide. But if you are planning on going with something smaller, or even fully ITB; then the desk can be shrunk too.
Your video screens are too high as well, and need to come down lower.
Also, are you planning to keep the Adam A7X's? They are pretty good speakers, so no problems there. Just asking.
I have looked at various mode calculators etc and all the rules of thumb like 38% from the front wall etc. However, in my room the true back wall is only a small part of the rear surface of the room. The longest point in the room is a patio door which is 54 - 55cm beyond the actual wall.
Ah yes! My favorite subject! Control room layout. The first rule here is to forget the rules...

Well, not all of them, but most of them. Forge the equilateral triangle rule, and the 38% rule, for example. Those do work... sort of... in most rooms... but they are not necessarily optimal for any room.
I would suggest starting out with your speakers 110cm from the side walls, 122cm above the floor, and with a 10cm gap between the rear corner of the speaker and the front wall. You will later insert a 10cm thick absorption panel in that gap. The first two numbers refer to the acoustic axis of the speaker, NOT the top or bottom of the cabinet, NOT the center of the front panel, and NOT the center of the tweeter (more mythical "rules" debunked). To estimate where the acoustic axis is on your speakers: draw an imaginary line from the center of the woofer to the center of the tweeter: the acoustic axis is located about midway along that imaginary line, and extends out perpendicular to the front face of the speaker. That's the reference point for all speaker measurements.
Then set up your mic so the tip is 187 cm from the front wall, on the room center line, and 120 cm above the floor, angled upwards at around 70° or so. That marks the center of where your head will be. Now set up a vertical pole of some type, such as a mic stand, so that the pole is about 30cm behind your head, on the room center line, and perfectly vertical. Aim both of your speakers at that pole. An easy way is to temporarily tape a laser pointer onto the top of the speaker, directly above the acoustic axis, and making sure that it is set exactly at right angles to the front face of the speaker. Then it's easy to rotate each speaker on its stand so the laser hits the pole, while keeping the side-wall-to-axis distance correct, and the rear-corner-to-front-wall distance correct. When both laser dots hit the middle of the pole in the same spot, and the distances are correct, then you have the correct INITIAL layout, for doing a set of REW tests that I have developed, to help you locate an even better spot... I'll send you the instructions for that privately. Not for public consumption!
What do I consider the dimensions of the room for any calculations?
Average. So take the widest width and the narrowest width (ignoring the bookshelf alcove), and average them: that's your width. Ditto for the height. Same for the rear wall, but just use the glass, as that's most of the rear wall, with just small sections on each side. Bare in mid that the wavelengths we are worried about here are many, many meters long, so high precision is not necessary.
Can I just split the difference and take an average width and height?
Yup!
How accurate does any average need to be?
A few cm is fine. Your modal issues are mainly around 100 Hz (give or take a hundred...). The wavelength at 100 Hz is 344cm, so if your measurement is off by 5cm (about 2"), that's only a bit more than 1%. Not a big deal, at this stage.
2. I need to control some serious dips in the bass response and some modal ringing down there too.
See above: Subs is the answer. Two of them, carefully set up and tuned in a plane wave bass array.
Should I just keep piling more rock wool in? I'm running out of space
You do need more bass trapping, yes, and it needs to go on the rear wall... or should I say, rear window...
Should I try and target specific modes with helmholtz devices or go for a wider range with panel absorbers?
You can tune either type either broad (low Q) or narrow (high Q). There's pro's and con's either way, but before deciding what to to, get your subs in: there's probably other monsters lurking down there in the mud that you haven't seen yet, but that you might need to treat. Your lowest axial mode at about 34 Hz is slightly visible, whimpering softly, but put some subs in there and it will probably roar... Then we'll need fiddle with the subs a bit to get that roar back down to a groan, and perhaps treat it with some tuned devices.
3. What can I do about the back wall that isn't a wall?
Put bass trapping on there!
I can't cover them with solid bass traps.
Then you can't get good acoustics in that room! Plain and simple answer, but not the one you wanted. The rear wall of any small room is always the biggest issue, and always needs the most treatment. Take a look here:
thread about Steve's high-end control room in New Orleans There's over 50cm depth of treatment across the entire back wall, and 90cm depth in the corners. You've seen the corner control room thread, and that has nearly 80cm depth into the corner, plus more on the side walls. Rear walls are ugly acoustic killers, and they need treatment. I would suggest building "treatment on wheels", sort of like gobos, that you can wheel into place in front of the windows when you need to do critical listening, then wheel out of the way when you want light.
as double glazed doors aren't great acoustic insulators maybe this works to my advantage by letting a lot of the bass pass straight through like an open window.
In theory, that's nice... but you can see that it isn't actually working for you in practice. Your first three lengthwise modes are theoretically 1.0.0= 33.97 Hz. 2.0.0= 67.94 Hz. 3.0.0= 101.9 Hz. Take a look around those spots on your REW waterfalls, and you can see all three of those monsters roaring and yelling... So that theory is out the window for your room! The modes are there, and very active. They are not going out through the glass, sad to say.
Could I try moveable absorbers or some sort (I previously had a couple of broadband absorbers on legs making gobos but they were a pain for getting in and out. I also had a curtain across the full back wall but this contributed to making the room very dull and dark. Maybe some form of heavy but partially reflective curtain such as a MLV or something?
Movable, yes, but not tiny little thin ineffective things like curtains and MLV. Think BIG. No, BIGGER! I mean REALLY B-I-G! The wavelength for your 68 Hz problem is 5.05m. It will just laugh at curtains and limp MLV. In fact, it won't even bother looking at them. To get useful damping, you'd need low density insulation about 1/16 wavelength, so about 31cm thick. And floor to ceiling. And at least one third of the room width on each side.
Tuned traps, such as slats, perf panel, rigid membrane, or limp membrane can be shallower, yes, but they still need to be big... because you have several issues, and each trap can only deal with one issue, so you need several traps... and they have to be large enough to take a serious bite out of the problem: if you make them matchbox size, they won't do anything. Neither show-box size. More like '70"-flat-screen-TV-box' size...
4. How can I stop the room being too dull?
By tuning it!

Use thick plastic across the front faces of those traps that only treat bass or high mids, thinner plastic across traps that treat up higher, slats across traps the treat down lower. There are simple equations for figuring out the thickness of the plastic vs. frequency, and the dimensions and spacing of the slats too.
OK, that should give you some food for thought! Personally, my tow major suggestions here would be to get a pair of good subs and a controller, and to add more bass trapping, but tuned it to not suck up the highs and mids. Watch out for killing the 200-500 Hz range: it's very easy to over-damp that. There's already some signs you are doing that around 350 Hz...
- Stuart -